Neosilyllithium catalyzed hydroboration of alkynes and alkenes in presence of pinacolborane (HBpin)
نویسندگان
چکیده
Catalytic hydroboration of alkynes and alkenes was well demonstrated in the presence neosilyllithium as catalyst pinacolborane, under ambient conditions, to form corresponding alkyl boronic ester products excellent yield. Electron-withdrawing, electron-donating substituents, were tolerated on phenyl rings styrenes. Further, aliphatic substituents yielded desired boronate good quantities. The mechanism product formation studied using theoretical calculations.
منابع مشابه
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ژورنال
عنوان ژورنال: European Journal of Inorganic Chemistry
سال: 2021
ISSN: ['1434-1948', '1099-0682']
DOI: https://doi.org/10.1002/ejic.202100895